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Stereoselective Synthesis of 4,5-Dihydroisoxazole Derivatives from 1,1-Dicyanocyclopropanes and Hydroxylamine Hydrochloride

期刊: HELVETICA CHIMICA ACTA, 2021; 104 (6)

An efficient approach was developed for the synthesis of 4,5-dihydroisoxazole derivatives from substituted 1,1-dicyano-cyclopropanes and hydroxylamine......

Fe-Catalyzed Intramolecular Cross-Dehydrogenative Arylation (CDA), Efficient Synthesis of 1-Arylnaphthalenes and 4-Arylcoumarins

期刊: HELVETICA CHIMICA ACTA, 2021; 104 (7)

Direct cross-dehydrogenative coupling of different inert C-H bonds is the most straightforward and environmentally benign method to construct C-C bond......

Synthesis of Enantiopure Benzo Fused Cyclic Sulfoximines Through Stereoselective [3+2] Cycloaddition between N-tert-Butanesulfinyl [(2-Pyridyl)sulfonyl]-difluoromethyl Ketimines and Arynes

期刊: HELVETICA CHIMICA ACTA, ; ()

The previously developed stereoselective [3+2] cycloaddition between N-tert-butanesulfinyl ketimines and arynes has been extended to the synthesis of ......

Phenazine Radical Cations as Efficient Homogeneous and Heterogeneous Catalysts for the Cross-Dehydrogenative Aza-Henry Reaction

期刊: HELVETICA CHIMICA ACTA, 2020; 103 (12)

The redox activity of molecular phenazine catalysts has been previously exploited for aerobic oxidative amine homo- and cross-coupling reactions. In t......

Transition Metal-Free Alkyne-Aldehyde Reductive C-C Coupling trough Cascade Borylation/Olefin Isomerization

期刊: HELVETICA CHIMICA ACTA, 2020; 103 (5)

A direct approach to gamma-keto esters through cascade alkyne-aldehyde reductive C-C coupling of propargyl esters and aromatic aldehydes under transit......

Synthesis of Ahod Moiety of Ralstonin A Using Amino Acid Schiff Base Ni(II)-Complex Chemistry

期刊: HELVETICA CHIMICA ACTA, 2020; 103 (7)

Reported here is the asymmetric synthesis of N-Boc-protected (2S,3S)-3-amino-2-hydroxyoctadecanoic acid, a component of ralstonin A and ralstoamide A.......

Synthesis of Benzo[a]carbazoles through Visible Light-Induced Cycloaromatization

期刊: HELVETICA CHIMICA ACTA, 2020; 103 (8)

We report herein a synthesis of 5,6-diarylbenzo[a]carbazoles by a sequence of 6 pi-electrocyclization followed by beta-elimination. The highly functio......

Base-Mediated N-Arylation for the Synthesis of 9H-Pyrrolo[1,2-a]indol-9-ones and 10H-Indolo[1,2-a]indol-10-ones

期刊: HELVETICA CHIMICA ACTA, 2019; 102 (1)

Treatment of 2-bromoaryl pyrrole/indol-2-yl ketones with cesium carbonate in DMF resulted in the formation of 9H-pyrrolo[1,2-a]indol-9-ones and 10H-in......

JIF:1.39

Enantioselective Total Synthesis of (-)-Doliculide Using Catalytic Asymmetric Hydrogenations

期刊: HELVETICA CHIMICA ACTA, 2019; 102 (3)

A concise and efficient strategy has been developed to construct a polyketide chain by employing relay asymmetric hydrogenations catalyzed by two chir......

JIF:1.39

Nickel-Catalyzed Cascade Annulation for the Rapid Synthesis of Carbocyclic Nitriles

期刊: HELVETICA CHIMICA ACTA, 2019; 102 (5)

We report a Ni-catalyzed cascade annulation reaction that proceeds through two sequential carbometallation steps followed by C-CN reductive eliminatio......

JIF:1.39

Multi-Gram Scale Synthesis of Chiral 3-Methyl-2,5-trans-tetrahydrofurans

期刊: HELVETICA CHIMICA ACTA, 2019; 102 (7)

In this article, we report the rapid and facile synthesis of chiral 3-methyl-2,5-trans-tetrahydrofurans. This reaction utilizes cheap and easily avail......

JIF:1.39

Retro-Corey-Chaykovsky Epoxidation: Converting Geminal Disubstituted Epoxides to Ketones

期刊: HELVETICA CHIMICA ACTA, 2019; 102 (9)

Corey-Chaykovsky epoxidation has been widely applied in the conversion of aldehydes and ketones to epoxides with sulfonium and sulfoxonium ylides. The......

JIF:1.39

PhI Catalyzed Acetoxyselenylation and Formyloxyselenylation of Alkenes

期刊: HELVETICA CHIMICA ACTA, 2017; 100 (3)

With PhI as catalyst and mCPBA as oxidant, a novel and efficient catalytic procedure has been developed for the acetoxyselenylation and formyloxyselen......

JIF:1.08

8-Hydroxy Quinoline Derivatives as Auxiliary Ligands for Red-Emitting Cyclic-Platinum Phosphorescent Complexes: Synthesis and Properties

期刊: HELVETICA CHIMICA ACTA, 2017; 100 (4)

Heavy metal complexes exhibit high phosphorescent efficiency and have been used extensively for electrophosphorescent emitters in the past 16 years. I......

JIF:1.08

Novel Dendritic PNP Chromium Complexes: Synthesis, Characterization, and Performance on Ethylene Oligomerization

期刊: HELVETICA CHIMICA ACTA, 2017; 100 (12)

Three dendritic PNP ligands with ethylenediamine, 1,4-butanediamine, 1,6-diaminohexane as bridged groups are synthesized in good yields, respectively.......

JIF:1.08

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