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Manganese-Catalyzed Batch and Continuous Flow Cationic RAFT Polymerization Induced by Visible Light

期刊: ACS MACRO LETTERS, 2021; 10 (5)

We present a robust manganese-catalyzed cationic reversible addition-fragmentation chain transfer (RAFT) polymerization induced by visible light. Well......

Crowding-Induced Unconventional Phase Behaviors in Dendritic Rodlike Molecules via Side-Chain Engineering

期刊: ACS MACRO LETTERS, 2021; 10 (7)

Dendritic molecules with a fanlike or conelike conformation are common molecular building blocks to construct supramolecular columnar or spherical pha......

Enhanced Electro-actuation in Dielectric Elastomers: The Nonlinear Effect of Free Ions

期刊: ACS MACRO LETTERS, 2021; 10 (4)

Plasticized poly(vinyl chloride) (PVC) is a jelly-like soft dielectric material that attracted substantial interest recently as a new type of electro-......

Bioinspired Polyurethane Using Multifunctional Block Modules with Synergistic Dynamic Bonds

期刊: ACS MACRO LETTERS, 2021; 10 (5)

Nature embraces an intriguing strategy to create high-performance biomaterials, such as spider silk which presents an unparalleled combination of stif......

Surface-Grafted Poly(ionic liquid) that Lubricates in Both Non-polar and Polar Solvents

期刊: ACS MACRO LETTERS, 2021; 10 (7)

We show that a surface-grafted polymer brush, 1-n-butyl-3-vinyl imidazolium bromide-based poly(ionic liquids), is able to reduce the interfacial frict......

MicroRNA-Responsive DNA-Programmed Nanomedicine with Controllability of Cascaded Events for Cancer Therapy Enhancement

期刊: ACS MACRO LETTERS, 2021; 10 (6)

Chemotherapy is a prime tool for cancer clinical therapy. The effectiveness has been improved considerably with the assistance of nanotechnology. Howe......

Photodeformable Azobenzene-Containing Polyimide with Flexible Linkers and Molecular Alignment

期刊: ACS MACRO LETTERS, 2021; 10 (4)

Azobenzene-containing polyimides (azo-PIs) as photodeformable materials have attracted scientific attention in view of combining photoresponse and hig......

On-Demand Regulation of Dual Thermosensitive Protein Hydrogels

期刊: ACS MACRO LETTERS, 2021; 10 (4)

Despite considerable progress having been made in thermosensitive protein hydrogels, regulating their thermal transitions remains a challenge due to t......

Hierarchical Assembly of Two-Dimensional Polymers into Colloidosomes and Microcapsules

期刊: ACS MACRO LETTERS, 2021; 10 (7)

Hierarchical assembly of two-dimensional (2D) polymers to 3D microstructures provides new means of creating functional materials with exotic propertie......

Chiral Liquid Crystalline Elastomer for Twisting Motion without Preset Alignment of Mesogens

期刊: ACS MACRO LETTERS, 2021; 10 (6)

A chiral liquid crystalline elastomer (CLCE) actuator is demonstrated. The solution-cast polydomain film of CLCE can twist upon order-disorder phase t......

Nanostructured Multiphase Condensation of Complex Coacervates in Polymerization-Induced Electrostatic Self-Assembly

期刊: ACS MACRO LETTERS, 2021; 10 (7)

We present the nanostructured multiphase condensation of complex coacervates in the dynamic evolving aqueous medium of liquid-liquid phase separation ......

Weakening of Solvation-Induced Ordering by Composition Fluctuation in Salt-Doped Block Polymers

期刊: ACS MACRO LETTERS, 2021; 10 (5)

The spontaneous ordering of block polymers doped with ions is affected by both selective solvation and long-range Coulombic interaction. The mean-fiel......

Self-Healing Metallacycle-Cored Supramolecular Polymers Based on a Metal-Salen Complex Constructed by Orthogonal Metal Coordination and Host-Guest Interaction with Amino Acid Sensing

期刊: ACS MACRO LETTERS, 2021; 10 (7)

A platinum(II) metallacycle-cored supramolecular network based on a metal-salen complex was successfully constructed by two orthogonal noncovalent int......

Direct Arylation Polycondensation toward Water/Alcohol-Soluble Conjugated Polymers: Influence of Side Chain Functional Groups

期刊: ACS MACRO LETTERS, 2021; 10 (4)

Direct arylation of 2,7-dibromofluorene with n-octyl, 6-diethoxylphosphorylhexyl, 6-(N,N-diethylamino)hexyl or 6-bromohexyl side chains and 1,2,4,5-te......

Green Fluorescent Tripeptide Nanostructures: Synergetic Effects of Oxidation and Hierarchical Assembly

期刊: ACS MACRO LETTERS, 2021; 10 (7)

Peptide-based fluorescent materials hold promise for applications in energy harvesting and biomedicine. One remaining challenge is to overcome the bar......

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