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Switchable Aromatic Nanopore Structures: Functions and Applications

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (14)

Nanopore structures in nature play a crucial role in performing many sophisticated functions such as signal transduction, mass transport, ion channel,......

Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (14)

Metal carbene plays a vital role in modern organic synthesis. The neutral divalent carbon of metal carbene renders it an active intermediate throughou......

Confined Crystallization of Polymers within Nanopores

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (15)

Crystallization of polymeric materials under nanoscopic confinement is highly relevant for nanotechnology applications. When a polymer is confined wit......

From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole C-H Bonds

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (7)

The widespread presence of hydrocarbons makes C-H functionalization an attractive alternative to traditional cross-coupling methods. As indole is an i......

Imaging Commensal Microbiota and Pathogenic Bacteria in the Gut

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (9)

CONSPECTUS: As a newly discovered organ, gut microbiota has been extensively studied in the last two decades, with their highly diverse and fundamenta......

Rational Design of Electrochemiluminescent Devices

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (14)

Electrochemiluminescence (ECL) is a light-emitting process which combines the intriguing merits of both electrochemical and chemiluminescent methods. ......

Mechanistic Diversity of Low-Valent Chromium Catalysis: Cross-Coupling and Hydrofunctionalization

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (8)

CONSPECTUS: Transition-metal catalysis has traditionally been dominated by precious metals because of their high reactivity toward chemical transforma......

Visualizing the Sensitive Lithium with Atomic Precision: Cryogenic Electron Microscopy for Batteries

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (9)

CONSPECTUS: Lithium (Li)-metal batteries are one of the most promising candidates for the next-generation energy storage devices due to their ultrahig......

Surface Fingerprinting of Faceted Metal Oxides and Porous Zeolite Catalysts by Probe-Assisted Solid-State NMR Approaches

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (10)

Acid catalysis in heterogeneous systems such as metal oxides and porous zeolites has been widely involved in various catalytic processes for chemical ......

Synthesis of C2+ Chemicals from CO2 and H-2 via C-C Bond Formation

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (10)

The severity of global warming necessitates urgent CO2 mitigation strategies. Notably, CO2 is a cheap, abundant, and renewable carbon resource, and it......

Ionic-Liquid-Catalyzed Approaches under Metal-Free Conditions

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (16)

Metal-free catalysis is a promising protocol to access chemicals without metal contamination. Ionic liquids (ILs) that are entirely composed of organi......

Supramolecular Purely Organic Room-Temperature Phosphorescence

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (17)

CONSPECTUS: In recent years, purely organic room-temperature phosphorescence (RTP) has aroused wide concern and promotes the development of the supram......

Symmetry-Breaking Sites for Activating Linear Carbon Dioxide Molecules

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (6)

CONSPECTUS: CO2 is not only a greenhouse gas but also a pivotal carbon source as a promising supplement to fossil fuels. Both the environment and ener......

Quantum Dots: A Promising Fluorescent Label for Probing Virus Trafficking

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (14)

Recent research has highlighted the immense potential of the quantum dot (QD)-based single-virus tracking (SVT) technique in virology. In these experi......

Metalla-aromatics: Planar, Nonplanar, and Spiro

期刊: ACCOUNTS OF CHEMICAL RESEARCH, 2021; 54 (9)

CONSPECTUS: The concept of aromaticity is one of the most fundamental principles in chemistry. It is generally accepted that planarity is a prerequisi......

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