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Isolated metal atoms and clusters for alkane activation: Translating knowledge from enzymatic and homogeneous to heterogeneous systems

期刊: CHEM, 2021; 7 (9)

Activation of alkanes can be achieved with different types of catalysts, spanning over enzymes, homogeneous and heterogeneous metal catalysts. Though ......

Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase

期刊: CHEM, 2021; 7 (9)

FAPbI(3) (FA(+) = formamidinium) perovskite, one of the most efficient basic components in nowadays perovskite solar cells (PCSs), undergoes spontaneo......

Intercepting a labile anti-pi-allyl-iridium complex before its isomerization

期刊: CHEM, 2021; 7 (3)

The stereodefined installation of chiral centers adjacent to thermo-dynamically unstable Z-olefins is a challenge in synthetic chemistry. In a recent ......

Field-induced oscillation of magnetization blocking barrier in a holmium metallacrown single-molecule magnet

期刊: CHEM, 2021; 7 (4)

Single-molecule magnets (SMMs) exhibit magnetization blocking in the presence of strong magnetic anisotropy. By employing molecular engineering, the b......

Reversibly modulating a conformation-adaptive fluorophore in [2]catenane

期刊: CHEM, 2021; 7 (6)

Tuning molecular emission by chemicalmeans has long been a fundamental topic, because the emerging methodologies and mechanisms of this topic usually ......

Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound

期刊: CHEM, 2021; 7 (4)

Photocatalytic co-production of high value-added multicarbon compounds and hydrogen from renewable bioethanol is an environmental and long-term approa......

Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles

期刊: CHEM, 2021; 7 (6)

Photosensitization under near-infrared (NIR) excitation is attractive for applications in photocatalysis and theragnostics because NIR light offers de......

Ligand coordination- and dissociation-induced divergent allylic alkylations using alkynes

期刊: CHEM, 2021; 7 (3)

In transition metal catalysis, the nature of ligand coordination plays a vital role in defining the reactivity of the catalytic system. Achieving mult......

The chemical states of conjugated coordination polymers

期刊: CHEM, 2021; 7 (5)

Conjugated coordination polymers (CCPs) with extended pi-d conjugation can effectively facilitate the delocalization of charges, form a continuous ele......

Visualization of the intermediates in organic catalytic reaction by single-molecule electrical spectroscopy

期刊: CHEM, 2021; 7 (9)

The capture and characterization of highly reactive and short-lived intermediates in organic catalytic reactions are challenging yet are very importan......

DNA-catalyzed efficient production of single-stranded DNA nanostructures

期刊: CHEM, 2021; 7 (4)

Single-stranded (ss) DNA nanostructures (DNs), created by unimolecular folding of kilo-based ssDNA, represent a new class of DNA constructs suitable f......

An axial-to-axial chirality transfer strategy for atroposelective construction of C-N axial chirality

期刊: CHEM, 2021; 7 (7)

C-N axially chiral skeletons are ubiquitous in bioactive natural products, pharmaceuticals, and chiral ligands. However, their atroposelective synthes......

Artificial light-triggered smart nanochannels relying on optoionic effects

期刊: CHEM, 2021; 7 (7)

Light-triggered smart nanochannels based on optoionic effects are currently explored in the fields of nanoconfined ion management and photoelectric co......

A see-through electrochromic display via dynamic metal-ligand interactions

期刊: CHEM, 2021; 7 (5)

Inspired by the dynamic coordination and dissociation between metal ions and ligands involved in biochemical reactions, we proposed and explored in de......

Synthetic tuning of the quantum properties of open-shell radicaloids

期刊: CHEM, 2021; 7 (5)

Open-shell molecular radicaloids could constitute the key to molecular quantum information and quantum sensing technologies. The effect of their morph......

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