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Experimental and computational study of the exchange interaction between the V(iii) centers in the vanadium-cyclal dimer

Reiss, A; Reimann, MK; Jin, CY; Wachter-Lehn, M; Kremer, RK; Pöttgen, R; Fink, K; Klopper, W; Feldmann, C

Feldmann, C (通讯作者),Karlsruhe Inst Technol KIT, Inst Anorgan Chem, Engesser Str 15, D-76131 Karlsruhe, Germany.;Klopper, W (通讯作者),Karlsruhe Inst Technol KIT, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany.;Klopper, W (通讯作者),Karlsruhe Inst Technol KIT, Inst Phys Chem, Fritz Haber Weg 2, D-76131 Karlsruhe, Germany.

DALTON TRANSACTIONS, 2023; 52 (46): 17389

Abstract

[V-2(HCyclal)(2)] is prepared by controlled oxidation of vanadium nanoparticles at 50 degrees C in toluene. The V(0) nanoparticles are synthesized in ......

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