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Bluer Phototruncation: Retro-Diels-Alder of Heptamethine Cyanine to Trimethine Cyanine through an Allene Hydroperoxide Intermediate

Lapoot, L; Wang, CN; Matikonda, SS; Schnermann, MJ; Greer, A

Greer, A (通讯作者),Brooklyn Coll, Dept Chem, Brooklyn, NY 11210 USA.;Greer, A (通讯作者),CUNY, Ph D Program Biochem, Grad Ctr, New York, NY 10016 USA.;Schnermann, MJ (通讯作者),NCI, Ctr Canc Res, Chem Biol Lab, Frederick, MD 21702 USA.;Greer, A (通讯作者),CUNY, Grad Ctr, Ph D Program Chem, New York, NY 10016 USA.

JOURNAL OF ORGANIC CHEMISTRY, 2023; 88 (24): 17430

Abstract

The photoconversion of heptamethine to pentamethine cyanines and of pentamethine to trimethine cyanines was recently reported. Here, we report mechani......

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