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Total Synthesis of (-)-Oridonin: An Interrupted Nazarov Approach

Kong, LR; Su, F; Yu, H; Jiang, Z; Lu, YD; Luo, TP

Luo, TP (reprint author), Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China.; Luo, TP (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019; 141 (51): 20048

Abstract

An enantioselective total synthesis of (-)-oridonin is accomplished based on a key interrupted Nazarov reaction. The stereochemistry of the Nazarov/Ho......

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