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The Transition Metal Catalyzed [pi 2s+pi 2s+sigma 2s+sigma 2s] Pericyclic Reaction: Woodward-Hoffmann Rules, Aromaticity, and Electron Flow

Cusumano, AQ; Goddard, WA; Stoltz, BM

Stoltz, BM (corresponding author), CALTECH, Warren & Katharine Schlinger Lab Chem & Chem Engn, Div Chem & Chem Engn, Pasadena, CA 91125 USA.; Goddard, WA (corresponding author), CALTECH, Beckman Inst, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020; 142 (45): 19033

Abstract

We have shown that the fundamental step responsible for enantioinduction in the inner-sphere asymmetric Tsuji allylic alkylation is C-C bond formation......

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