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Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C-S Bond Homolysis in a Mixed Valence Diiron Dithiolate

Li, Q; Lalaoui, N; Woods, TJ; Rauchfuss, TB; Arrigoni, F; Zampella, G

Rauchfuss, TB (reprint author), Univ Illinois, Sch Chem Sci, 505 S Mathews Ave, Urbana, IL 61801 USA.; Zampella, G (reprint author), Univ Milano Bicocca, Dept Biotechnol & Biosci, Piazza Sci 2, I-20126 Milan, Italy.

INORGANIC CHEMISTRY, 2018; 57 (8): 4409

Abstract

The synthesis and redox properties are presented for the electron-rich bis(monothiolate)s Fe-2(SR)2(-) (CO)(2)(dppv)(2) for R = Me ([1](0)), Ph ([2](0......

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