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Halogen-Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis-Trifluoromethyl-beta-Diketiminates and the Dual Role of LiCH2I

Ielo, L; Castoldi, L; Touqeer, S; Lombino, J; Roller, A; Prandi, C; Holzer, W; Pace, V

Pace, V (corresponding author), Univ Vienna, Dept Pharmaceut Chem, Althanstr 14, A-1090 Vienna, Austria.; Pace, V (corresponding author), Univ Turin, Dept Chem, Via P Giuria 7, I-10125 Turin, Italy.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020; 59 (47): 20852

Abstract

The selective formal insertion (homologation) of a carbon unit bridging the two trifluoroacetamidoyl chlorides (TFAICs) units is reported. The tactic ......

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