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Cooperation towards nobility: equipping first-row transition metals with an aluminium sword

期刊: DALTON TRANSACTIONS, 2023; 52 (40)

The exploration for noble metals substitutes in catalysis has become a highly active area of research, driven by the pursuit of sustainable chemical p......

Phase transition behaviour and mechanism of 2D TiO2(B) nanosheets through water-mediated removal of surface ligands

期刊: DALTON TRANSACTIONS, 2023; 52 (42)

Phase engineering is a central subject in materials research. The recent research interest in the phase transition behavior of atomically thin 2D mate......

Effects of proton tunneling distance on CO2 reduction by Mn terpyridine species

期刊: DALTON TRANSACTIONS, 2023; 52 (40)

Herein, we report two manganese terpyridine dicarbonyl complexes, covalently attached to a proximal (1) or distal (2) amide moiety at the ortho positi......

A fluorescent controllable supramolecular crosslinked polymer constructed by complementary metal coordination interaction

期刊: DALTON TRANSACTIONS, 2023; 52 (40)

In this work, two different monomers M1 and M2 were designed and synthesized. M1 + M2 + Zn(OTf)2 could self-assemble to form a supramolecular crosslin......

Structure-activity effects in the anti-leishmanial activity of di-alkyl gallium quinolin-8-olates

期刊: DALTON TRANSACTIONS, 2023; 52 (43)

Six (G1-G6) novel organogallium complexes of the general formula [Ga(R)2quin] (where R = Et, iPr, nBu, tBu, sBu and hexyl; quin = quinolin-8-olate, C9......

Phosphinoborenium cations stabilized by N-heterocyclic carbenes: synthesis, structure, and reactivity

期刊: DALTON TRANSACTIONS, 2023; 52 (43)

Phosphinoborenium cations stabilized by N-heterocyclic carbenes (NHCs) were synthesized via the reaction of bromo(phosphino)boranes with NHCs. Their s......

Co-MOF@MWCNTs/GCE for the sensitive detection of TBHQ in food samples

期刊: DALTON TRANSACTIONS, 2023; 52 (45)

tert-Butylhydroquinone (TBHQ) is a novel synthetic antioxidant with a higher safety profile and antioxidant effect that is more excellent than other s......

Design of polymetallic sulfide NiS2@Co4S3@FeS as bifunctional catalyst for high efficiency seawater splitting

期刊: DALTON TRANSACTIONS, 2023; 52 (45)

The shortage of freshwater resources in the world today has limited the development of water splitting, and our eyes have turned to the abundant seawa......

Defective silicotungstic acid-loaded magnetic floral N-doped carbon microspheres for ultra-fast oxidative desulfurization of high sulfur liquid fuels

期刊: DALTON TRANSACTIONS, 2023; 52 (46)

Highly active Keggin-type silicotungstic acid (SiW12) with oxygen vacancy (Ov) defects was encapsulated into the magnetic floral N-doped carbon micros......

Experimental and computational study of the exchange interaction between the V(iii) centers in the vanadium-cyclal dimer

期刊: DALTON TRANSACTIONS, 2023; 52 (46)

[V-2(HCyclal)(2)] is prepared by controlled oxidation of vanadium nanoparticles at 50 degrees C in toluene. The V(0) nanoparticles are synthesized in ......

Filling the gaps of uranium oxide hydrates with magnesium(II) ions: unique layered structures and the role of additional sodium(I) ions

期刊: DALTON TRANSACTIONS, 2023; 52 (47)

Alkaline earth metal ions play an important role in the formation of secondary uranium minerals due to their abundance in the Earth's crust. Although ......

Design and oxidative desulfurization of Ag/Ti heterometallic clusters based on Hard-Soft Acid-Base principle

期刊: DALTON TRANSACTIONS, 2023; 52 (47)

Hard-Soft Acid-Base (HSAB) principle plays an important guiding role in the design and synthesis of novel clusters and coordination compounds, in whic......

Nanotubular Fe2O3 and Mn3O4 with hierarchical porosity as high-performance anode materials for lithium-ion batteries

期刊: DALTON TRANSACTIONS, 2023; 52 (48)

Developing eco-friendly and low-cost advanced anode materials, such as Fe2O3 and Mn3O4, is fundamental to improve the electrochemical performance of l......

Theoretical study of copper hydride complexes catalyzing terminal alkyne hydroalkylation for C(sp2)-C(sp3) bond formation

期刊: DALTON TRANSACTIONS, 2023; 53 (1)

This study applies Density Functional Theory (DFT) to theoretically investigate the reaction mechanism of a copper complex catalyst facilitating the r......

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