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Oxidative Functionalization of Trinor-18 alpha-olean-17(22)-ene Derivatives. Annulation of the E-Ring by an Intramolecular Aldol Reaction

Kuczynska, K; Jazwinski, J; Pakulski, Z; Cmoch, P; Luboradzki, R

Kuczynska, K; Pakulski, Z (corresponding author), Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland.

JOURNAL OF ORGANIC CHEMISTRY, 2021; 86 (11): 7636

Abstract

cis-Dihydroxylation of trinor-18 alpha-olean-17(22)-ene 2 with osmium tetroxide led to diol 9. Its cleavage with lead tetraacetate gave tetracyclic ke......

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